|Blue to blue-green gel or crystalline powder|
|80° C (176° F)|
SECTION 1. IDENTIFICATION
Product Name: Copper Hydroxide
Product Number: all applicable American facets product codes, e.g. CU-OH-02, CU-OH-025, CU-OH-03, CU-OH-035, CU-OH-04, CU-OH-05
CAS #: 20427-59-2
Relevant identified uses the the substance: clinical research and development
Emergency call number:Domestic, phibìc America: +1 800-424-9300International: +1 703-527-3887
SECTION 2. Dangers IDENTIFICATION
Classification the the substance or mixture in accordance with 29 CFR 1910 (OSHA HCS)GHS05 CorrosionEye Dam. 1 H318 causes serious eye damage.GHS07Acute Tox. 4 H302 Harmful if swallowed.Skin Irrit. 2H315 causes skin irritation.STOT SE 3 H335 May cause respiratory irritation.Hazards no otherwise classifiedNo data availableGHS label elementsGHS brand elements, consisting of precautionary statementsHazard pictograms
GHS05 GHS07Signal wordDangerHazard statementsH302 Harmful if swallowed.H315 reasons skin irritation.H318 causes serious eye damage.H335 May reason respiratory irritation.Precautionary statementsP261Avoid breathing dust/fume/gas/mist/vapors/spray.P280Wear security gloves/protective clothing/eye protection/face protection.P305+P351+P338 IF IN EYES: to wash cautiously through water for numerous minutes. Remove contact lenses, if present and also easy to do. Continue rinsing.P304+P340IF INHALED: Remove human to fresh air and also keep comfortable for breathing.P405Store locked up.P501Dispose of contents/container in accordance v local/regional/national/international regulations.WHMIS classificationD2B - toxic material leading to other toxic effectsClassification systemHMIS ratings (scale 0-4)(Hazardous materials Identification System)Health (acute effects) = 2Flammability = 0Physical hazard = 0Other hazardsResults the PBT and also vPvB assessmentPBT:N/AvPvB:N/A
SECTION 3. COMPOSITION/INFORMATION on INGREDIENTS
SubstancesCAS No. / substance Name:20427-59-2 Copper(II) hydroxideIdentification number(s):EC number: 243-815-9Impurities and stabilizing additives:Stabilizer is present however may vary.
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SECTION 4. Very first AID MEASURES
Description of very first aid measuresGeneral informationTake influenced persons out into the fresh air.If inhaled:In situation of unconsciousness place patient stably in side position for transportation.Supply patient through fresh air. If not breathing, administer artificial respiration. Save patient warm.Seek prompt medical advice.In instance of skin contact:Immediately wash with soap and also water; wash thoroughly.Seek prompt medical advice.In situation of eye contact:Rinse opened up eye for number of minutes under running water. Consult a physician.If swallowed:Drink several water.Induce vomiting if patience is conscious.Information for doctorMost essential symptoms and also effects, both acute and also delayedNo data availableIndication of any type of immediate clinical attention and special therapy neededNo data available
SECTION 5. FIREFIGHTING MEASURES
Extinguishing mediaSuitable extinguishing agentsCarbon dioxide, extinguishing powder or water spray. Fight bigger fires with water spray or alcohol resistant foam.Product is no flammable. Use fire-fighting procedures that suit the neighboring fire.Special hazards arising from the substance or mixtureIf this product is affiliated in a fire, the following can be released:Copper oxidesAdvice because that firefightersProtective equipment:Wear self-contained respirator.Wear completely protective impervious suit.
SECTION 6. ACCIDENTAL release MEASURES
Personal precautions, protective equipment and emergency proceduresUse personal protective equipment. Save unprotected persons away.Ensure enough ventilationEnvironmental precautions:Do not enable to get in sewers/ surface or groundwater.Methods and materials for containment and also cleanup:Prevent development of dust.Dispose of contaminated product as waste follow to section 13.Ensure sufficient ventilation.Prevention of an additional hazards:No special actions required.Reference to other sectionsSee section 7 for information on for sure handlingSee section 8 for info on an individual protection equipment.See section 13 because that disposal information.
SECTION 7. HANDLING and also STORAGE
HandlingPrecautions for for sure handlingHandle under dried protective gas.Keep container strictly sealed.Store in cool, dry place in tightly closeup of the door containers.Ensure good ventilation in ~ the workplace.Information around protection against explosions and also fires:The product is not flammableConditions for for sure storage, including any kind of incompatibilitiesRequirements to it is in met by storerooms and receptacles:No special requirements.Information about storage in one usual storage facility:Store far from water/moisture.Do not store along with acids.Store far from oxidizing agents.Further information around storage conditions:Store under dry inert gas.This product is hygroscopic.Keep container tightly sealed.Store in cool, dry conditions in well-sealed containers.Protect native humidity and also water.Specific finish use(s)No data available
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Additional information around design of technical systems:Properly operation chemical fume hood designed because that hazardous chemicals and having one average face velocity that at the very least 100 feet every minute.Control parametersComponents v limit worths that call for monitoring in ~ the workplace:None.Additional information:The exposure limits that were valid when the MSDS was created were used.No dataExposure controlsPersonal protective equipmentFollow usual protective and hygienic practices for handling chemicals.Keep far from foodstuffs, beverages and also feed.Remove every soiled and also contaminated garments immediately.Wash hands before breaks and at the end of work.Avoid call with the eyes and skin.Maintain one ergonomically suitable working environment.Breathing equipment:Use an ideal respirator as soon as high concentrations are present.In situation of short exposure or low pollution use respiratory tract filter device. In case of extensive or longer exposure usage respiratory protective maker that is elevation of turn around air.Recommended filter an equipment for short term use:Filter P2Use a respirator with type N95 (USA) or PE (EN 143) cartridges together a back-up to engineering controls. Risk assessment need to be perform to recognize if air-purifying respirators space appropriate. Just use devices tested and also approved under ideal government standards.Protection that hands:Impervious glovesProtective gloves.Inspect gloves before use.Suitability that gloves must be identified both by material and quality, the latter of which may vary through manufacturer.Material that glovesNitrile rubber, NBRPenetration time of glove product (in minutes)No data availableEye protection:Tightly sealed gogglesBody protection:Protective occupational clothing.
SECTION 9. PHYSICAL and CHEMICAL PROPERTIES
Information on simple physical and chemical propertiesAppearance:Form: PowderColor: BlueOdor: OdorlessOdor threshold: No data available.pH: N/AMelting point/Melting range: NoneBoiling point/Boiling range: NoneSublimation temperature / start: No data availableFlash point: N/AFlammability (solid, gas)Product is no flammable.Ignition temperature: No data availableDecomposition temperature: No data availableAutoignition: No data available.Danger of explosion: Product go not present an explosion hazard.Explosion limits:Lower: No data availableUpper: No data availableVapor pressure: N/ADensity at 20 Â°C (68 Â°F): 3.4 g/cmÂ3 (28.373 lbs/gal)Relative densityNo data available.Vapor densityN/AEvaporation rateN/ASolubility in Water (H2O): InsolublePartition coefficient (n-octanol/water): No data available.Viscosity:Dynamic: N/AKinematic: N/AOther informationNo data available
SECTION 10. STABILITY and REACTIVITY
ReactivityNo data availableChemical stabilityStable under recommended storage conditions.Thermal decomposition / conditions to it is in avoided:Decomposes before melting.Possibility that hazardous reactionsReacts with strong oxidizing agentsConditions to avoidNo data availableIncompatible materials:AcidsWater/moistureOxidizing agentsHazardous decomposition products:Metal oxide fumeCopper oxidesAdditional information:Avoid lose of stabilizer.
SECTION 11. TOXICOLOGICAL INFORMATION
Information on toxicological effectsAcute toxicity:Harmful if swallowed.The it is registered of Toxic impacts of chemistry Substances (RTECS) has acute toxicity data because that this substance.LD/LC50 worths that are appropriate for classification:OralLD50 1000 mg/kg (rat)Dermal LD50 >3160 mg/kg (rabbit)Skin irritation or corrosion:No irritant effect.Causes skin irritation.Eye wake up or corrosion:Irritating effect.Causes major eye damage.Sensitization:No sensitizing effects known.Germ cell mutagenicity:No results known.Carcinogenicity:EPA-D: no classifiable as to human carcinogenicity: inadequate human and also animal proof of carcinogenicity or no data are available.Reproductive toxicity:No effects known.Specific target organ system toxicity - repeated exposure:No results known.Specific target organ system toxicity - single exposure:May reason respiratory irritation.Aspiration hazard:No impacts known.Subacute to chronic toxicity:No effects known.Additional toxicological information:To the finest of our knowledge the acute and chronic toxicity the this problem is not totally known.The substance is not subject to classification.
SECTION 12. Environmental INFORMATION
ToxicityAquatic toxicity:No data availablePersistence and also degradabilityNo data availableBioaccumulative potentialNo data availableMobility in soilNo data availableAdditional environmental information:The product has not yet been evaluate by the commission for the evaluation of products hazardous come water. Until the commission has actually reached that is verdict, the product is evaluated together hazardous come water (WKG 2) in accordance with the recommendations of the VCI (self-evaluation concept).Do not permit product to with groundwater, water courses, or sewage systems.Do not enable material to be exit to the atmosphere without main permits.Danger to drink water if even little quantities leak right into the ground.Avoid transfer into the environment.Results of PBT and also vPvB assessmentPBT:N/AvPvB:N/AOther disadvantage effectsNo data available
SECTION 13. Disposal CONSIDERATIONS
Waste treatment methodsRecommendationConsult main regulations to ensure suitable disposal.Waste disposal vital number according to the european Waste Catalogue:06 04 99Uncleaned packagings:Recommendation:Disposal must be made according to main regulations.
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SECTION 14. Move INFORMATION
UN-NumberDOT, ADN, IMDG, IATAN/AUN appropriate shipping nameDOT, ADN, IMDG, IATAN/ATransport peril class(es)DOT, ADR, ADN, IMDG, IATAClassN/APacking groupDOT, IMDG, IATAN/AEnvironmental hazards:N/ASpecial precautions because that userN/ATransport in mass according to Annex II that MARPOL73/78 and the IBC CodeN/ATransport/Additional information:DOTMarine Pollutant (DOT):No
SECTION 15. Regulation INFORMATION
Safety, health and environmental regulations/legislation certain for the problem or mixtureGHS GHS brand elements, consisting of precautionary statementsHazard pictogramsGHS05GHS07Signal wordDangerHazard statementsH302 Harmful if swallowed.H315 causes skin irritation.H318 reasons serious eye damage.H335 May cause respiratory irritation.Precautionary statementsP261Avoid breathing dust/fume/gas/mist/vapors/spray.P280Wear protective gloves/protective clothing/eye protection/face protection.P305+P351+P338 IF IN EYES: wash cautiously through water for number of minutes. Remove contact lenses, if present and easy to do. Continue rinsing.P304+P340IF INHALED: Remove person to new air and also keep comfortable because that breathing.P405Store locked up.P501Dispose that contents/container in accordance with local/regional/national/international regulations.National regulationsAll components of this product are noted in the U.S. Ecological Protection agency Toxic Substances manage Act chemical substance Inventory.All contents of this product are detailed on the Canadian residential Substances perform (DSL).SARA section 313 (specific toxic chemical listings)20427-59-2 Copper(II) hydroxideCalifornia Proposition 65Prop 65 - Chemicals known to reason cancerSubstance is no listed.Prop 65 - Developmental toxicitySubstance is no listed.Prop 65 - Developmental toxicity, femaleSubstance is no listed.Prop 65 - Developmental toxicity, maleSubstance is not listed.Information around limitation of use:For use only by technically qualified individuals.Other regulations, limitations and also prohibitive regulationsSubstance of really High concern (SVHC) according to the reach Regulations (EC) No. 1907/2006.Substance is no listed.The problems of constraints according to post 67 and also Annex XVII the the Regulation (EC) No 1907/2006 (REACH) because that the manufacturing, place on the market and use must be observed.Substance is no listed.Annex XIV the the with Regulations (requiring Authorisation because that use)Substance is no listed.Chemical safety and security assessment:A Chemical safety Assessment has not been carried out.SECTION 16. Various other INFORMATION